Thulium(III) oxalate
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3D model (JSmol)
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| ChemSpider | |
| ECHA InfoCard | 100.019.898 |
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PubChem CID
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CompTox Dashboard (EPA)
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| Properties | |
| Tm2(C2O4)3 | |
| Appearance | solid |
| Hazards | |
| GHS labelling:[1] | |
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| Warning | |
| H302, H312 | |
| P264, P270, P280, P301+P317, P302+P352, P317, P321, P330, P362+P364, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Thulium(III) oxalate is the oxalate of thulium with the chemical formula Tm2(C2O4)3. Its hydrate can be prepared by reacting an aqueous solution of thulium(III) chloride and a benzene solution of dimethyl oxalate.[2] Its pentahydrate is decomposed by heat to obtain the dihydrate, which is further heated to obtain thulium(III) oxide.[3] It reacts with hydrochloric acid to obtain H[Tm(C2O4)2]·6H2O.[4]
References
[edit]- ^ "Thulium(3+) oxalate". pubchem.ncbi.nlm.nih.gov. Retrieved 29 February 2024.
- ^ Mamoru Watanabe, Kozo Nagashima (Oct 1971). "Hydrated oxalates of the yttrium group rare earth elements and scandium". Journal of Inorganic and Nuclear Chemistry. 33 (10): 3604–3608. doi:10.1016/0022-1902(71)80691-7. Archived from the original on 2020-10-15. Retrieved 2020-10-11.
- ^ Wendlandt, W. W. (1959). "Thermal Decomposition of Rare Earth Metal Oxalates". Analytical Chemistry. 31 (3): 408–410. doi:10.1021/ac60147a024. ISSN 0003-2700.
- ^ Moebius, R.; Matthes, F. The exchange of oxalate ions for chloride ions of the oxalate hydrates of the rare earths and yttrium. Zeitschrift fuer Chemie, 1964. 4 (6): 234-235. ISSN: 0044-2402.